{"id":2738,"date":"2016-10-26T15:31:11","date_gmt":"2016-10-26T15:31:11","guid":{"rendered":"http:\/\/nanowizard.info\/?p=2738"},"modified":"2016-10-26T15:31:11","modified_gmt":"2016-10-26T15:31:11","slug":"some-like-it-hot-carbon-dioxide-reduction-visible-and-near-infrared-photothermal-catalyzed-hydrogenation-of-gaseous-co2-over-nanostructured-pdnb2o5","status":"publish","type":"post","link":"http:\/\/nanowizard.info\/?p=2738","title":{"rendered":"Some like it Hot: Carbon Dioxide Reduction: Visible and Near-Infrared Photothermal Catalyzed Hydrogenation of Gaseous CO2 over Nanostructured Pd@Nb2O5"},"content":{"rendered":"<p><a href=\"http:\/\/nanowizard.info\/wp-content\/media\/20161012_Ozin_AdvScience.jpg\"><img loading=\"lazy\" class=\"alignleft size-full wp-image-1112\" title=\"Cover Final\" src=\"http:\/\/nanowizard.info\/wp-content\/media\/20161012_Ozin_AdvScience.jpg\" alt=\"\" width=\"234\" height=\"189\" \/><\/a><\/p>\n<blockquote><p>Geoffry A. Ozin and co-workers demonstrate that the reverse water gas shift (RWGS) reaction, driven by a visible and near infrared responsive Pd@Nb2O5 is thermally activated with measured conversion rates as high as 1.8 mmol gcat<sup>\u22121<\/sup> h<sup>\u22121<\/sup>, Advanced Science, 2016, DOI: 10.1002\/advs.201670051. Specifically, the RWGS reaction is enabled by heat generated from thermalization of photoexcited charge carriers in the Pd nanocrystals that function as \u201cnanoheaters\u201d for the entire Pd@Nb2O5 assembly, through non-radiative relaxation of inter-band and intra-band conduction electron transitions. Overall this study advances our understanding of the underlying mechanism of photothermally driven CO2 reduction. Cover illustration by Chenxi Qian.<\/p><\/blockquote>\n","protected":false},"excerpt":{"rendered":"<p>Geoffry A. Ozin and co-workers demonstrate that the reverse water gas shift (RWGS) reaction, driven by a visible and near infrared responsive Pd@Nb2O5 is thermally activated with measured conversion rates as high as 1.8 mmol gcat\u22121 h\u22121, Advanced Science, 2016, &hellip; <a href=\"http:\/\/nanowizard.info\/?p=2738\">Continue reading <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":22,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[],"_links":{"self":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts\/2738"}],"collection":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/users\/22"}],"replies":[{"embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2738"}],"version-history":[{"count":3,"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts\/2738\/revisions"}],"predecessor-version":[{"id":2741,"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts\/2738\/revisions\/2741"}],"wp:attachment":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2738"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2738"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2738"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}