{"id":3682,"date":"2019-09-16T16:54:27","date_gmt":"2019-09-16T16:54:27","guid":{"rendered":"http:\/\/nanowizard.info\/?p=3682"},"modified":"2019-09-16T16:57:19","modified_gmt":"2019-09-16T16:57:19","slug":"congratulations-to-young-and-co-authors-on-their-article-in-jacs","status":"publish","type":"post","link":"http:\/\/nanowizard.info\/?p=3682","title":{"rendered":"Congratulations to Young and co-authors on their article in JACS"},"content":{"rendered":"<p><a href=\"http:\/\/nanowizard.info\/wp-content\/media\/Cu-PdWO3.jpg\"><img loading=\"lazy\" class=\"alignleft size-full wp-image-1112\" title=\"Cover Final\" src=\"http:\/\/nanowizard.info\/wp-content\/media\/Cu-PdWO3.jpg\" alt=\"\" width=\"234\" height=\"189\" \/><\/a><\/p>\n<blockquote><p>Atomically precise heterostrucutures present chemically interesting active sites for catalysis but are often expensive and\/or challenging to synthesize. In this article, we report a synthetic strategy to conformally coating Cu atoms onto the surface of Pd\/HyWO3-x by anchoring Cu(I)OtBu to the Br\u00f8nsted acidic protons of the bronze. It was observed that just 0.2 at.% of Cu was able to increase the catalytic performance of CO2 hydrogenation to CO by 500%. This metal anchoring method enables atom precise modification of the surfaces of metal oxide nanomaterials for catalytic applications, circumventing the need for complex and expensive atomic layer deposition processes.<\/p>\n<p>See full article at <a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.9b08030\">Journal of the American Chemical Society<\/a>.<\/p><\/blockquote>\n","protected":false},"excerpt":{"rendered":"<p>Atomically precise heterostrucutures present chemically interesting active sites for catalysis but are often expensive and\/or challenging to synthesize. In this article, we report a synthetic strategy to conformally coating Cu atoms onto the surface of Pd\/HyWO3-x by anchoring Cu(I)OtBu to &hellip; <a href=\"http:\/\/nanowizard.info\/?p=3682\">Continue reading <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":22,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[],"_links":{"self":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts\/3682"}],"collection":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/users\/22"}],"replies":[{"embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3682"}],"version-history":[{"count":5,"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts\/3682\/revisions"}],"predecessor-version":[{"id":3688,"href":"http:\/\/nanowizard.info\/index.php?rest_route=\/wp\/v2\/posts\/3682\/revisions\/3688"}],"wp:attachment":[{"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3682"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=3682"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/nanowizard.info\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=3682"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}