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Recent Posts
- Congratulations to Geoff’s solar ethene and hydrogen paper on Matter
- Congratulations to Geoff’s heterogeneous catalysis paper on Matter
- Congratulations to Geoff’s birthday paper of CO2 photocatalysis on Matter
- Could modified train cars capture carbon from the air? This team has a plan to make it happen
- Sand batteries that are dirt cheap
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Congratulations to Young and co-authors on their article in JACS
Atomically precise heterostrucutures present chemically interesting active sites for catalysis but are often expensive and/or challenging to synthesize. In this article, we report a synthetic strategy to conformally coating Cu atoms onto the surface of Pd/HyWO3-x by anchoring Cu(I)OtBu to … Continue reading
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Congratulations to Lili Wan, Wei Sun, & co-authors on their article in Nature Catalysis
A long-standing challenge in the field of CO2 utilization is how to stabilize Cu2O, an earth-abundant, non-toxic, low-cost (photo)catalyst that can facilitate reduction of CO2 to CO against the irreversible redox disproportionation Cu2O → Cu + CuO, responsible for its … Continue reading
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Congratulations to Dr. Zaiyong Jiang et al. on their paper, “Building a Bridge from Papermaking to Solar Fuels
Everybody knows the leaf makes carbohydrates and the trunk makes paper. But did you know that waste from the paper making process can make fuel from carbon dioxide, water and sunlight? Black liquor, an industrial waste product of papermaking, is … Continue reading
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Congratulations to Zaiyong Jiang, Wei Sun, & co-authors on their article in Advanced Science
In their paper, “Living Atomically Dispersed Cu Ultrathin TiO2 Nanosheet CO2 Reduction Photocatalyst”, Jiang, Sun, and co-authors report a serendipitous living photodeposition method can make atomically dispersed Cu immobilized on ultrathin TiO2 nanosheets, which can photocatalytically reduce an aqueous solution … Continue reading
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Fundamentals and Applications of Photocatalytic CO2 Methanation
The extraction and combustion of fossil natural gas, consisting primarily of methane, generates vast amounts of greenhouse gases that contribute to climate change. However, as a result of recent research efforts, “solar methane” can now be produced through the photo-catalytic … Continue reading
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Challenges of Electrifying Heterogeneous Catalysis
How can we replace the fossil-fuel-derived heat that conventionally drives chemical processes with an emissions-free alternative? The current standard in industrial-scale heterogeneous catalytic processes, such as the production of ammonia and hydrogen, is to use heat supplied by the combustion … Continue reading
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Electrochemical Carbon Dioxide Reduction in Supercritical Carbon Dioxide is Cool
At standard temperature and pressure, CO2 exists as a gas. On cooling to -78.5 °C, it becomes a solid called dry ice, which is a common refrigerant. At a critical temperature of 31.1 °C and pressure 72.9 atmospheres, however, CO2 … Continue reading
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Congratulations to Dr. Xiaoliang Yan and co-authors on their paper, “Nickel@Siloxene catalytic nanosheets for high-performance CO2 methanation”
wo-dimensional materials hold great potential as catalysts for the heterogeneous conversion of CO2 to synthetic fuels and chemicals. In this paper, Yan et al. demonstrate the performance of nickel@siloxene to be highly sensitive to the nickel component being located either … Continue reading
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Congratulations to Dr. Tingjiang Yan and co-authors on their paper, “Polymorph selection towards photocatalytic gaseous CO2 hydrogenation”
Titanium dioxide is the only known material that can enable gas-phase CO2 photocatalysis in its anatase and rutile polymorphic forms. In their paper, however, Dr. Yan and co-authors demonstrate that the lesser known rhombohedral polymorph of indium sesquioxide, like its … Continue reading
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Electricity-free Renewable Hydrogen
A recent paper published in the Proceedings of the National Academy of Science has reported that applying carbon capture and utilization (CCU) to manufacture the top 20 commodity chemicals could mitigate up to of 3.5 gigatonnes of carbon emmisions annually, … Continue reading
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